Because cap isn't based on total skill points, but on formulas where skills have different value
Mvps can cap at 100 and they can at 140 as well, it all depends on distribution of skills
If I look at the NT skills requirements for Austrias national team, I have a hard time believing those players are possible when their core skills exceed the cap level for most potential levels including MVP.
Lord of All the Beasts, Fishes & Hoes in the Milky Way aka Drip God from Vienna